! Revised Condensed SAPRC07 Mechanism, CS07B. Version 1/12/10
!
! Uses standard SAPRC-07 peroxy radical operators with coefficient parameters
! for rates of peroxy radical operator reactions
!
! Note: # 'coef' means rate constant is coefficient value, where the 'coef'
! value is calculated at each time step, as follows (where K<label> refers
! to rate constant for labeled reaction, and C<species> referrs to species
! concentrations.
!
SPECIAL =
'RO2NO' = K<BR07>*C<NO>;
'RO2HO2' = K<BR08>*C<HO2>;
'RO2NO3' = K<BR09>*C<NO3>;
'RO2RO2' = K<BR11>*C<RO2C> + K<BR11>*C<RO2XC>;
'RO2RO3' = K<BR25>*C<MECO3> + K<BR25>*C<RCO3>;
'RO2RO' = 'RO2NO' + 'RO2NO3' + 'RO2RO3' + 0.5*'RO2RO2';
'RO2XRO' = 'RO2HO2' + (0.5*'RO2RO2');
'RO2RO2M' = 0.5*'RO2RO2';
'RO22NN' = 'RO2NO3' + 'RO2RO3' + 0.5*'RO2RO2';
!
! Base Mechanism
! Atmospheric Lumped VOC Mechanism
! Base Chlorine Mechanism
! Chlorine + Atmospheric Lumped VOC Mechanism
!
REACTIONS(CM) =
!
! -----------------------------------------------------------------
! Base Mechanism
! Created from MECH09B.XLS 25-Jan-2010 12:56
!
<1> NO2 = NO + O3P # 1.0/<NO2-06>;
<2> O3P + O2 + M = O3 # 5.68e-34^-2.60;
<3> O3P + O3 =  # 8.00e-12@2060;
<4> O3P + NO = NO2 # 9.00e-32^-1.50&3.00e-11&0.60&1.00;
<5> O3P + NO2 = NO # 5.50e-12@-188;
<6> O3P + NO2 = NO3 # 2.50e-31^-1.80&2.20e-11^-0.70&0.60&1.00;
<7> O3 + NO = NO2 # 3.00e-12@1500;
<8> O3 + NO2 = NO3 # 1.40e-13@2470;
<9> NO + NO3 = 2*NO2 # 1.80e-11@-110;
<10> NO + NO + O2 = 2*NO2 # 3.30e-39@-530;
<11> NO2 + NO3 = N2O5 # 3.60e-30^-4.10&1.90e-12^0.20&0.35&1.33;
<12> N2O5 = NO2 + NO3 # 1.30e-03^-3.50@11000&9.70e+14^0.10@11080&0.35&1.33;
<13> N2O5 + H2O = 2*HNO3 # 2.50e-22;
<14> N2O5 + H2O + H2O = 2*HNO3 # 1.80e-39;
<15> NO2 + NO3 = NO + NO2 # 4.50e-14@1260;
<16> NO3 = NO # 1.0/<NO3NO-06>;
<17> NO3 = NO2 + O3P # 1.0/<NO3NO2-6>;
<18> O3 = O1D # 1.0/<O3O1D-06>;
<19> O3 = O3P # 1.0/<O3O3P-06>;
<20> O1D + H2O = 2*OH # 1.63e-10@-60;
<21> O1D + M = O3P # 2.38e-11@-96;
<22> OH + NO = HONO # 7.00e-31^-2.60&3.60e-11^-0.10&0.60&1.00;
<23> HONO = OH + NO # 1.0/<HONO-06>;
<24> OH + HONO = NO2 # 2.50e-12@-260;
<25> OH + NO2 = HNO3 # 1.80e-30^-3.00&2.80e-11&0.60&1.00;
<26> OH + NO3 = HO2 + NO2 # 2.00e-11;
<27> OH + HNO3 = NO3 %2 # 2.40e-14@-460&2.70e-17@-2199&6.50e-34@-1335;
<28> HNO3 = OH + NO2 # 1.0/<HNO3>;
<29> OH + CO = HO2 + CO2 %3 # 1.44e-13@0&3.43e-33@0;
<30> OH + O3 = HO2 # 1.70e-12@940;
<31> HO2 + NO = OH + NO2 # 3.60e-12@-270;
<32> HO2 + NO2 = HNO4 # 2.00e-31^-3.40&2.90e-12^-1.10&0.60&1.00;
<33> HNO4 = HO2 + NO2 # 3.72e-05^-2.40@10650&5.42e+15^-2.30@11170&0.60&1.00;
<34> HNO4 = 0.61*HO2 + 0.61*NO2 + 0.39*OH + 0.39*NO3 # 1.0/<HNO4-06>;
<35> HNO4 + OH = NO2 # 1.30e-12@-380;
<36> HO2 + O3 = OH # 2.03e-16^4.57@-693;
<37> HO2 + HO2 = HO2H %3 # 2.20e-13@-600&1.90e-33@-980;
<38> HO2 + HO2 + H2O = HO2H %3 # 3.08e-34@-2800&2.66e-54@-3180;
<39> NO3 + HO2 = 0.8*OH + 0.8*NO2 + 0.2*HNO3 # 4.00e-12;
<40> NO3 + NO3 = 2*NO2 # 8.50e-13@2450;
<41> HO2H = 2*OH # 1.0/<H2O2>;
<42> HO2H + OH = HO2 # 1.80e-12;
<43> OH + HO2 =  # 4.80e-11@-250;
<44> OH + SO2 = HO2 + SULF # 3.30e-31^-4.30&1.60e-12&0.60&1.00;
<45> OH + H2 = HO2 # 7.70e-12@2100;
<BR07> RO2C + NO = NO2 # 2.60e-12@-380;
<BR08> RO2C + HO2 =  # 3.80e-13@-900;
<BR09> RO2C + NO3 = NO2 # 2.30e-12;
<BR11> RO2C + RO2C =  # 3.50e-14;
<BR12> RO2XC + NO = XN # 1.0*K<BR07>;
<BR13> RO2XC + HO2 =  # 1.0*K<BR08>;
<BR14> RO2XC + NO3 = NO2 # 1.0*K<BR09>;
<BR16> RO2XC + RO2C =  # 1.0*K<BR11>;
<BR17> RO2XC + RO2XC =  # 1.0*K<BR11>;
<BR18> MECO3 + NO2 = PAN # 2.70e-28^-7.10&1.21e-11^-0.90&0.30&1.41;
<BR19> PAN = MECO3 + NO2 # 4.90e-03@12100&4.00e+16@13600&0.30&1.41;
<BR20> PAN = 0.6*MECO3 + 0.6*NO2 + 0.4*RO2C + 0.4*xHO2 + 0.4*xHCHO + 0.4*yROOH +
         0.4*CO2 + 0.4*NO3 # 1.0/<PAN>;
<BR21> MECO3 + NO = RO2C + xHO2 + xHCHO + yROOH + CO2 + NO2 # 7.50e-12@-290;
<BR22> MECO3 + HO2 = 0.243*ALK3 + 0.086*CCHO + 0.3*O3 + 0.856*XC
        # 5.20e-13@-980;
<BR23> MECO3 + NO3 = RO2C + xHO2 + xHCHO + yROOH + CO2 + NO2 # 1.0*K<BR09>;
<BR25> MECO3 + RO2C = RO2C + xHO2 + xHCHO + yROOH + CO2 # 4.40e-13@-1070;
<BR26> MECO3 + RO2XC = RO2C + xHO2 + xHCHO + yROOH + CO2 # 1.0*K<BR25>;
<BR27> MECO3 + MECO3 = 2*RO2C + 2*xHO2 + 2*xHCHO + 2*yROOH + 2*CO2
        # 2.90e-12@-500;
<BR28> RCO3 + NO2 = PAN2 # 1.21e-11^-1.07@0;
<BR29> PAN2 = RCO3 + NO2 # 8.30e+16@13940;
<BR30> PAN2 = 0.6*RCO3 + 0.6*NO2 + 0.4*RO2C + 0.4*xHO2 + 0.4*yROOH + 0.4*xCCHO +
         0.4*CO2 + 0.4*NO3 # 1.0/<PAN>;
<BR31> RCO3 + NO = NO2 + RO2C + xHO2 + yROOH + xCCHO + CO2 # 6.70e-12@-340;
<BR32> RCO3 + HO2 = 0.526*ALK3 + 0.19*CCHO + 0.25*O3 + 0.516*XC # 1.0*K<BR22>;
<BR33> RCO3 + NO3 = NO2 + RO2C + xHO2 + yROOH + xCCHO + CO2 # 1.0*K<BR09>;
<BR35> RCO3 + RO2C = RO2C + xHO2 + xCCHO + yROOH + CO2 # 1.0*K<BR25>;
<BR36> RCO3 + RO2XC = RO2C + xHO2 + xCCHO + yROOH + CO2 # 1.0*K<BR25>;
<BR37> RCO3 + MECO3 = 2*CO2 + RO2C + xHO2 + xHCHO + yROOH + RO2C + xHO2 +
         yROOH + xCCHO # 1.0*K<BR27>;
<BR38> RCO3 + RCO3 = 2*RO2C + 2*xHO2 + 2*xCCHO + 2*yROOH + 2*CO2 # 1.0*K<BR27>;
<BR66> BZO + NO2 = 0.5*CRES + 2.5*XC + XN # 2.30e-11@-150;
<BR67> BZO + HO2 = CRES + -1*XC # 1.0*K<BR08>;
<BR68> BZO = CRES + RO2C + xHO2 + -1*XC # 1.00e-03;
<RO01> xHO2 = HO2 # 'RO2RO';
<RO02> xHO2 =  # 'RO2XRO';
<RO03> xOH = OH # 'RO2RO';
<RO04> xOH =  # 'RO2XRO';
<RO05> xNO2 = NO2 # 'RO2RO';
<RO06> xNO2 = XN # 'RO2XRO';
<RO09> xMECO3 = MECO3 # 'RO2RO';
<RO10> xMECO3 = 2*XC # 'RO2XRO';
<RO11> xRCO3 = RCO3 # 'RO2RO';
<RO12> xRCO3 = 3*XC # 'RO2XRO';
<BP01> HCHO = 2*HO2 + CO # 1.0/<HCHOR-06>;
<BP02> HCHO = CO # 1.0/<HCHOM-06>;
<BP03> HCHO + OH = HO2 + CO # 5.40e-12@-135;
<BP07> HCHO + NO3 = HNO3 + HO2 + CO # 2.00e-12@2431;
<BP08> CCHO + OH = MECO3 # 4.40e-12@-365;
<BP09> CCHO = HO2 + xHO2 + RO2C + CO + xHCHO + yROOH # 1.0/<CCHO_R>;
<BP10> CCHO + NO3 = MECO3 + HNO3 # 1.40e-12@1860;
<BP11> RCHO + OH = 0.035*xHO2 + 0.965*RCO3 + 0.035*RO2C + 0.035*CO +
         0.035*xCCHO + 0.035*yROOH # 5.10e-12@-405;
<BP12> RCHO = HO2 + xHO2 + RO2C + CO + xCCHO + yROOH # 1.0/<C2CHO>;
<BP13> RCHO + NO3 = RCO3 + HNO3 # 1.40e-12@1601;
<BC24> ROOH + OH = 0.156*xHO2 + 0.798*OH + 0.028*xOH + 0.235*RO2C +
         0.018*RO2XC + 0.018*zRNO3 + 0.005*xHCHO + 0.016*xCCHO + 0.328*RCHO +
         0.132*xRCHO + 0.469*PRD2 + 0.062*xPROD2 + 0.202*yROOH + 0.289*XC
        # 4.23e-11;
<BP25> ROOH = 0.521*HO2 + 0.437*xHO2 + OH + 0.437*RO2C + 0.043*RO2XC +
         0.043*zRNO3 + 0.015*xCCHO + 0.489*RCHO + 0.032*xRCHO + 0.079*PRD2 +
         0.39*xPROD2 + 0.479*yROOH + 0.335*XC # 1.0/<COOH>;
<BP28> RAOOH + OH = 0.148*HO2 + 0.565*xHO2 + 0.139*OH + 0.024*xOH + 0.589*RO2C +
         0.124*RO2XC + 0.124*zRNO3 + 0.448*xRCHO + 0.147*MGLY + 0.26*xMGLY +
         0.139*IPRD + 0.077*xAFG1 + 0.147*xAFG2 + 0.074*PRD2 + 0.011*xPROD2 +
         0.713*yROOH + 2.366*XC # 1.41e-10;
<BP29> RAOOH = HO2 + OH + 0.661*MGLY + 0.584*AFG1 + 1.01*AFG2 + -1.951*XC
        # 1.0/<COOH>;
<BP34> MGLY = HO2 + MECO3 + CO # 1.0/<MGLY-06>;
<BP35> MGLY + OH = MECO3 + CO # 1.50e-11;
<BP36> MGLY + NO3 = MECO3 + HNO3 + CO # 1.40e-12@1895;
<BP38> CRES + OH = 0.8*xHO2 + 0.2*BZO + 0.8*RO2C + 0.25*xMGLY + 0.8*yROOH +
         5.05*XC # 1.70e-12@-950;
<BP39> CRES + NO3 = BZO + HNO3 + XC # 1.40e-11;
<BP46> AFG1 + OH = 0.521*xHO2 + 0.201*xMECO3 + 0.217*RCO3 + 0.723*RO2C +
         0.06*RO2XC + 0.06*zRNO3 + 0.334*CO + 0.407*xRCHO + 0.301*xMGLY +
         0.018*xAFG1 + 0.048*xPROD2 + 0.783*yROOH + 0.753*XC # 7.40e-11;
<BP47> AFG1 + O3 = 0.522*HO2 + 0.826*OH + 0.652*xRCO3 + 0.652*RO2C + 0.522*CO +
         0.174*CO2 + 0.652*xHCHO + 0.707*MGLY + 0.072*AFG1 + 0.652*yROOH +
         -0.786*XC # 9.66e-18;
<BP48> AFG1 = 1.023*HO2 + 0.173*xHO2 + 0.305*MECO3 + 0.5*RCO3 + 0.173*RO2C +
         0.695*CO + 0.173*xHCHO + 0.368*MGLY + 0.033*AFG1 + 0.173*yROOH +
         0.756*XC # 1.0/<AFG1>;
<BP49> AFG2 + OH = 0.521*xHO2 + 0.201*xMECO3 + 0.217*RCO3 + 0.723*RO2C +
         0.06*RO2XC + 0.06*zRNO3 + 0.334*CO + 0.407*xRCHO + 0.301*xMGLY +
         0.018*xAFG1 + 0.048*xPROD2 + 0.783*yROOH + 0.753*XC # 7.40e-11;
<BP50> AFG2 + O3 = 0.522*HO2 + 0.826*OH + 0.652*xRCO3 + 0.652*RO2C + 0.522*CO +
         0.174*CO2 + 0.652*xHCHO + 0.707*MGLY + 0.072*AFG1 + 0.652*yROOH +
         -0.786*XC # 9.66e-18;
<BP51> AFG2 = PRD2 + -1*XC # 1.0/<AFG1>;
<BP64> IPRD + OH = 0.496*xHO2 + 0.238*xMECO3 + 0.241*RCO3 + 0.734*RO2C +
         0.025*RO2XC + 0.025*zRNO3 + 0.238*CO + 0.149*xHCHO + 0.051*xCCHO +
         0.243*xRCHO + 0.215*xMGLY + 0.01*xAFG1 + 0.192*xPROD2 + 0.76*yROOH +
         0.587*XC # 6.19e-11;
<BP65> IPRD + O3 = 0.211*HO2 + 0.025*xHO2 + 0.219*OH + 0.053*xRCO3 +
         0.053*RO2C + 0.483*CO + 0.13*CO2 + 0.086*HCHO + 0.033*xHCHO +
         0.051*CCHO + 0.02*xCCHO + 0.86*MGLY + 0.002*AFG1 + 0.033*PRD2 +
         0.095*ALK3 + 0.053*yROOH + 0.8*XC # 4.18e-18;
<BP66> IPRD + NO3 = 0.792*xHO2 + 0.158*RCO3 + 0.792*RO2C + 0.05*RO2XC +
         0.05*zRNO3 + 0.158*HNO3 + 0.57*CO + 0.222*xHCHO + 0.213*xRCHO +
         0.008*xMGLY + 0.559*xRNO3 + 0.842*yROOH + 0.283*XN + -0.583*XC
        # 1.00e-13;
<BP67> IPRD = 0.655*HO2 + 0.141*xHO2 + 0.084*OH + 0.27*MECO3 + 0.084*xMECO3 +
         0.343*RCO3 + 0.225*RO2C + 0.867*CO + 0.204*HCHO + 0.225*xHCHO +
         0.184*CCHO + 0.246*PRD2 + 0.225*yROOH + 0.123*XC # 1.0/<MACR-06>;
<BP68> PRD2 + OH = 0.472*HO2 + 0.379*xHO2 + 0.029*xMECO3 + 0.049*xRCO3 +
         0.473*RO2C + 0.071*RO2XC + 0.071*zRNO3 + 0.002*HCHO + 0.211*xHCHO +
         0.001*CCHO + 0.083*xCCHO + 0.143*RCHO + 0.402*xRCHO + 0.329*PRD2 +
         0.049*xPROD2 + 0.528*yROOH + 1.082*XC # 1.55e-11;
<BP69> PRD2 = 0.913*xHO2 + 0.4*MECO3 + 0.6*RCO3 + 1.59*RO2C + 0.087*RO2XC +
         0.087*zRNO3 + 0.303*xHCHO + 0.163*xCCHO + 0.78*xRCHO + yROOH +
         -0.091*XC # 4.86e-3/<MEK-06>;
<BP70> RNO3 + OH = 0.189*HO2 + 0.305*xHO2 + 0.019*NO2 + 0.313*xNO2 +
         0.976*RO2C + 0.175*RO2XC + 0.175*zRNO3 + 0.011*xHCHO + 0.429*xCCHO +
         0.001*RCHO + 0.036*xRCHO + 0.012*PRD2 + 0.094*xPROD2 + 0.189*RNO3 +
         0.305*xRNO3 + 0.793*yROOH + 0.174*XN + 0.372*XC # 7.20e-12;
<BP71> RNO3 = 0.344*HO2 + 0.554*xHO2 + NO2 + 0.721*RO2C + 0.102*RO2XC +
         0.102*zRNO3 + 0.074*HCHO + 0.061*xHCHO + 0.214*CCHO + 0.23*xCCHO +
         0.074*RCHO + 0.063*xRCHO + 0.236*PRD2 + 0.292*xPROD2 + 0.657*yROOH +
         0.786*XC # 1.0/<IC3ONO2>;
<PO01> xHCHO = HCHO # 'RO2RO';
<PO02> xHCHO = XC # 'RO2XRO';
<PO03> xCCHO = CCHO # 'RO2RO';
<PO04> xCCHO = 2*XC # 'RO2XRO';
<PO05> xRCHO = RCHO # 'RO2RO';
<PO06> xRCHO = 3*XC # 'RO2XRO';
<PO11> xPROD2 = PRD2 # 'RO2RO';
<PO12> xPROD2 = 6*XC # 'RO2XRO';
<PO15> xMGLY = MGLY # 'RO2RO';
<PO16> xMGLY = 3*XC # 'RO2XRO';
<PO21> xAFG1 = AFG1 # 'RO2RO';
<PO22> xAFG1 = 5*XC # 'RO2XRO';
<PO23> xAFG2 = AFG2 # 'RO2RO';
<PO24> xAFG2 = 5*XC # 'RO2XRO';
<PO31> xIPRD = IPRD # 'RO2RO';
<PO32> xIPRD = 5*XC # 'RO2XRO';
<PO33> xRNO3 = RNO3 # 'RO2RO';
<PO34> xRNO3 = 6*XC + XN # 'RO2XRO';
<PO35> zRNO3 = RNO3 + -1*XN # 'RO2NO';
<PO36> zRNO3 = PRD2 + HO2 # 'RO22NN';
<PO37> zRNO3 = 6*XC # 'RO2XRO';
<PO38> yROOH = ROOH + -5*XC # 'RO2HO2';
<PO39> yROOH = PRD2 + -6*XC # 'RO2RO2M';
<PO40> yROOH =  # 'RO2RO';
<PO44> yRAOOH = RAOOH + -8*XC # 'RO2HO2';
<PO45> yRAOOH = PRD2 + -6*XC # 'RO2RO2M';
<PO46> yRAOOH =  # 'RO2RO';
<BE01> CH4 + OH = xHO2 + RO2C + xHCHO + yROOH # 1.85e-12@1690;
<BE02> ETHE + OH = xHO2 + RO2C + 1.61*xHCHO + 0.195*xCCHO + yROOH
        # 1.00e-28^-4.50&8.80e-12^-0.85&0.60&1.00;
<BE03> ETHE + O3 = 0.16*HO2 + 0.16*OH + 0.51*CO + 0.12*CO2 + HCHO + 0.032*CCHO +
         0.018*ALK3 + 0.235*XC # 9.14e-15@2580;
<BE04> ETHE + NO3 = xHO2 + RO2C + xRCHO + yROOH + XN + -1*XC
        # 3.30e-12^2.00@2880;
<BE05> ETHE + O3P = 0.8*HO2 + 0.8*xHO2 + 0.8*RO2C + 0.788*CO + 0.788*xHCHO +
         0.1*CCHO + 0.004*xMGLY + 0.002*xAFG1 + 0.8*yROOH + 0.202*XC
        # 1.07e-11@800;
<BE06> ISOP + OH = 0.907*xHO2 + 0.986*RO2C + 0.093*RO2XC + 0.093*zRNO3 +
         0.624*xHCHO + 0.907*xIPRD + yROOH + -0.717*XC # 2.54e-11@-410;
<BE07> ISOP + O3 = 0.066*HO2 + 0.266*OH + 0.192*xRCO3 + 0.192*RO2C +
         0.008*RO2XC + 0.008*zRNO3 + 0.275*CO + 0.122*CO2 + 0.4*HCHO +
         0.192*xHCHO + 0.018*CCHO + 0.7*IPRD + 0.1*PRD2 + 0.01*ALK3 +
         0.2*yROOH + -0.787*XC # 7.86e-15@1912;
<BE08> ISOP + NO3 = 0.749*xHO2 + 0.187*xNO2 + 0.936*RO2C + 0.064*RO2XC +
         0.064*zRNO3 + 0.936*xIPRD + yROOH + 0.813*XN + -0.064*XC
        # 3.03e-12@448;
<BE09> ISOP + O3P = 0.25*xHO2 + 0.24*xRCO3 + 0.49*RO2C + 0.01*RO2XC +
         0.01*zRNO3 + 0.49*xHCHO + 0.75*PRD2 + 0.5*yROOH + -0.77*XC # 3.50e-11;
!
! Atmospheric Lumped VOC Mechanism
! Created from MECH09B.XLS 25-Jan-2010 12:56
!
<BL03> ALK3 + OH = 0.931*xHO2 + 1.253*RO2C + 0.07*RO2XC + 0.07*zRNO3 +
         0.262*xHCHO + 0.445*xCCHO + 0.122*xRCHO + 0.141*xPROD2 + 1.236*yROOH +
         1.216*XC # 1.51e-12@-126;
<BLC4> ALK4 + OH = 0.766*xHO2 + 0.007*xMECO3 + 1.708*RO2C + 0.227*RO2XC +
         0.227*zRNO3 + 0.001*CO + 0.039*xHCHO + 0.31*xCCHO + 0.226*xRCHO +
         0.303*xPROD2 + 1.006*yROOH + 0.469*XC # 6.16e-12;
<BL06> OLE1 + OH = 0.905*xHO2 + 1.139*RO2C + 0.095*RO2XC + 0.095*zRNO3 +
         0.701*xHCHO + 0.301*xCCHO + 0.47*xRCHO + 0.04*xIPRD + 0.119*xPROD2 +
         1.001*yROOH + 0.801*XC # 6.18e-12@-501;
<BL07> OLE1 + O3 = 0.116*HO2 + 0.144*xHO2 + 0.193*OH + 0.167*RO2C +
         0.004*RO2XC + 0.004*zRNO3 + 0.368*CO + 0.125*CO2 + 0.5*HCHO +
         0.104*xHCHO + 0.184*CCHO + 0.007*xCCHO + 0.353*RCHO + 0.031*xRCHO +
         0.191*PRD2 + 0.073*ALK3 + 0.148*yROOH + 0.904*XC # 3.15e-15@1701;
<BL08> OLE1 + NO3 = 0.824*xHO2 + 1.312*RO2C + 0.176*RO2XC + 0.176*zRNO3 +
         0.009*xCCHO + 0.002*xRCHO + 0.002*xPROD2 + 0.546*xRNO3 + yROOH +
         0.454*XN + 0.634*XC # 4.73e-13@1047;
<BL09> OLE1 + O3P = 0.45*RCHO + 0.274*PRD2 + 2.004*XC # 1.49e-11@326;
<BL10> OLE2 + OH = 0.914*xHO2 + 0.966*RO2C + 0.086*RO2XC + 0.086*zRNO3 +
         0.209*xHCHO + 0.788*xCCHO + 0.481*xRCHO + 0.066*xIPRD + 0.06*xPROD2 +
         yROOH + 0.568*XC # 1.26e-11@-488;
<BL11> OLE2 + O3 = 0.093*HO2 + 0.329*xHO2 + 0.423*OH + 0.147*xMECO3 +
         0.008*xRCO3 + 0.49*RO2C + 0.003*RO2XC + 0.003*zRNO3 + 0.297*CO +
         0.162*CO2 + 0.152*HCHO + 0.398*xHCHO + 0.473*CCHO + 0.067*xCCHO +
         0.315*RCHO + 0.018*xRCHO + 0.049*IPRD + 0.057*PRD2 + 0.133*ALK3 +
         0.487*yROOH + 0.455*XC # 8.14e-15@1255;
<BL12> OLE2 + NO3 = 0.456*xHO2 + 0.409*xNO2 + 1.218*RO2C + 0.136*RO2XC +
         0.136*zRNO3 + 0.107*xHCHO + 0.546*xCCHO + 0.154*xRCHO + 0.033*xIPRD +
         0.009*xPROD2 + 0.322*xRNO3 + 1.033*yROOH + 0.269*XN + 0.375*XC
        # 2.20e-13@-382;
<BL13> OLE2 + O3P = 0.014*HO2 + 0.007*xHO2 + 0.007*xRCO3 + 0.013*RO2C +
         0.001*RO2XC + 0.001*zRNO3 + 0.006*CO + 0.074*RCHO + 0.006*xIPRD +
         0.464*PRD2 + 0.014*yROOH + 1.933*XC # 1.43e-11@-111;
<BL14> ARO1 + OH = 0.166*HO2 + 0.482*xHO2 + 0.284*OH + 0.482*RO2C +
         0.068*RO2XC + 0.068*zRNO3 + 0.201*MGLY + 0.208*xMGLY + 0.166*CRES +
         0.2*xAFG1 + 0.39*xAFG2 + 0.077*xPROD2 + 0.147*yROOH + 0.403*yRAOOH +
         0.789*XC # 6.15e-12;
<BL15> ARO2 + OH = 0.108*HO2 + 0.58*xHO2 + 0.202*OH + 0.58*RO2C + 0.11*RO2XC +
         0.11*zRNO3 + 0.143*MGLY + 0.532*xMGLY + 0.108*CRES + 0.236*xAFG1 +
         0.424*xAFG2 + 0.035*xPROD2 + 0.089*yROOH + 0.601*yRAOOH + 2.047*XC
        # 2.57e-11;
<BL16> TERP + OH = 0.759*xHO2 + 0.042*xRCO3 + 1.147*RO2C + 0.2*RO2XC +
         0.2*zRNO3 + 0.001*CO + 0.264*xHCHO + 0.533*xRCHO + 0.029*xMGLY +
         0.003*xIPRD + 0.259*xPROD2 + yROOH + 5.15*XC # 1.87e-11@-435;
<BL17> TERP + O3 = 0.052*HO2 + 0.067*xHO2 + 0.585*OH + 0.126*xMECO3 +
         0.149*xRCO3 + 0.875*RO2C + 0.203*RO2XC + 0.203*zRNO3 + 0.185*CO +
         0.045*CO2 + 0.079*HCHO + 0.15*xHCHO + 0.017*CCHO + 0.22*xRCHO +
         0.083*xMGLY + 0.002*xIPRD + 0.41*PRD2 + 0.012*xPROD2 + 0.028*ALK3 +
         0.545*yROOH + 4.026*XC # 9.57e-16@785;
<BL18> TERP + NO3 = 0.162*xHO2 + 0.421*xNO2 + 0.019*xRCO3 + 1.509*RO2C +
         0.397*RO2XC + 0.397*zRNO3 + 0.01*CO + 0.017*xHCHO + 0.001*xCCHO +
         0.509*xRCHO + 0.001*xMGLY + 0.006*xIPRD + 0.012*xPROD2 + 0.163*xRNO3 +
         yROOH + 0.416*XN + 4.919*XC # 1.28e-12@-490;
<BL19> TERP + O3P = 0.147*RCHO + 0.853*PRD2 + 4.441*XC # 3.71e-11;
!
! Base Chlorine Mechanism
! Created from MECH09B.XLS 25-Jan-2010 12:56
!
<CI01> CL2 = 2*CL # 1.0/<CL2>;
<CI08> CL + HO2 = HCL # 3.44e-11^-0.56;
<CI09> CL + HO2 = CLO + OH # 9.41e-12^2.10;
<CI10> CL + O3 = CLO # 2.80e-11@250;
<CI11> CL + NO3 = CLO + NO2 # 2.40e-11;
<CI12> CLO + NO = CL + NO2 # 6.20e-12@-295;
<CI13> CLO + NO2 = CLONO2 # 1.80e-31^-3.40&1.50e-11^-1.90&0.60&1.00;
<CI14> CLONO2 = CLO + NO2 # 1.0/<CLONO2-1>;
<CI15> CLONO2 = CL + NO3 # 1.0/<CLONO2-2>;
<CI16> CLONO2 = CLO + NO2 # 4.48e-05^-1.00@12530&3.71e+15^3.50@12530&0.60&1.00;
<CI17> CL + CLONO2 = CL2 + NO3 # 6.20e-12@-145;
<CI20> CLO + CLO = 0.29*CL2 + 1.42*CL # 1.25e-11@1960;
<CI21> OH + HCL = CL # 1.70e-12@230;
<CI22> CL + H2 = HCL + HO2 # 3.90e-11@2310;
<CP01> HCHO + CL = HCL + HO2 + CO # 8.10e-11@30;
<CP02> CCHO + CL = HCL + MECO3 # 8.00e-11;
<CP04> RCHO + CL = HCL + 0.1*xHO2 + 0.9*RCO3 + 0.1*RO2C + 0.1*CO + 0.1*xCCHO +
         0.1*yROOH # 1.23e-10;
<CP07> RNO3 + CL = HCL + 0.055*HO2 + 0.547*xHO2 + 0.038*NO2 + 0.159*xNO2 +
         1.282*RO2C + 0.202*RO2XC + 0.202*zRNO3 + 0.045*xHCHO + 0.3*xCCHO +
         0.009*RCHO + 0.02*xRCHO + 0.019*PRD2 + 0.061*xPROD2 + 0.055*RNO3 +
         0.547*xRNO3 + 0.907*yROOH + 0.201*XN + -0.036*XC # 1.92e-10;
<CP08> PRD2 + CL = HCL + 0.314*HO2 + 0.541*xHO2 + 0.007*xMECO3 + 0.022*xRCO3 +
         0.679*RO2C + 0.116*RO2XC + 0.116*zRNO3 + 0.237*xHCHO + 0.109*xCCHO +
         0.198*RCHO + 0.591*xRCHO + 0.116*PRD2 + 0.059*xPROD2 + 0.686*yROOH +
         1.353*XC # 2.00e-10;
<CP10> MGLY + CL = HCL + MECO3 + CO # 8.00e-11;
<CP11> CRES + CL = HCL + xHO2 + yROOH + 7*XC # 6.20e-11;
<CC13> ROOH + CL = HCL + 0.345*xHO2 + 0.264*OH + 0.326*xOH + 0.862*RO2C +
         0.065*RO2XC + 0.065*zRNO3 + 0.047*xHCHO + 0.15*xCCHO + 0.183*RCHO +
         0.465*xRCHO + 0.081*PRD2 + 0.202*xPROD2 + 0.737*yROOH + 0.618*XC
        # 2.41e-10;
<CP15> RAOOH + CL = 0.404*HCL + 0.148*HO2 + 0.565*xHO2 + 0.139*OH + 0.024*xOH +
         0.589*RO2C + 0.124*RO2XC + 0.124*zRNO3 + 0.448*xRCHO + 0.147*MGLY +
         0.26*xMGLY + 0.139*IPRD + 0.077*xAFG1 + 0.147*xAFG2 + 0.074*PRD2 +
         0.011*xPROD2 + 0.713*yROOH + 2.366*XC # 4.29e-10;
<CP18> IPRD + CL = 0.221*HCL + 0.033*HO2 + 0.597*xHO2 + 0.221*xMECO3 +
         0.102*RCO3 + 0.943*RO2C + 0.047*RO2XC + 0.047*zRNO3 + 0.333*CO +
         0.077*xHCHO + 0.259*xRCHO + 0.007*xMGLY + 0.066*xIPRD + 0.017*AFG1 +
         0.004*xAFG1 + 0.034*AFG2 + 0.008*xAFG2 + 0.865*yROOH + 2.114*XC
        # 4.12e-10;
<CP23> xCL = CL # 'RO2RO';
<CP24> xCL =  # 'RO2XRO';
<CE01> CH4 + CL = HCL + xHO2 + RO2C + xHCHO + yROOH # 7.30e-12@1280;
<CE02> ETHE + CL = xHO2 + 2*RO2C + xHCHO + XC
        # 1.60e-29^-3.30&3.10e-10^-1.00&0.60&1.00;
<CE03> ISOP + CL = 0.15*HCL + 0.738*xHO2 + 0.177*xCL + 1.168*RO2C +
         0.085*RO2XC + 0.085*zRNO3 + 0.275*xHCHO + 0.02*xRCHO + 0.848*xIPRD +
         yROOH + -0.085*XC # 4.80e-10;
!
! Chlorine + Atmospheric Lumped VOC Mechanism
! Created from MECH09B.XLS 25-Jan-2010 12:56
!
<BC03> ALK3 + CL = HCL + 0.929*xHO2 + 1.361*RO2C + 0.07*RO2XC + 0.07*zRNO3 +
         0.172*xHCHO + 0.34*xCCHO + 0.343*xRCHO + 0.105*xPROD2 + 1.094*yROOH +
         1.067*XC # 1.86e-10;
<CLC4> ALK4 + CL = HCL + 0.76*xHO2 + 0.002*xMECO3 + 1.664*RO2C + 0.237*RO2XC +
         0.237*zRNO3 + 0.002*CO + 0.031*xHCHO + 0.207*xCCHO + 0.353*xRCHO +
         0.26*xPROD2 + 1.002*yROOH + 0.507*XC # 3.20e-10;
<BC06> OLE1 + CL = 0.308*HCL + 0.902*xHO2 + 1.42*RO2C + 0.098*RO2XC +
         0.098*zRNO3 + 0.025*xHCHO + 0.146*xCCHO + 0.287*xRCHO + 0.229*xIPRD +
         yROOH + 2.09*XC # 3.55e-10;
<BC07> OLE2 + CL = 0.263*HCL + 0.448*xHO2 + 0.448*xCL + 1.515*RO2C +
         0.104*RO2XC + 0.104*zRNO3 + 0.229*xHCHO + 0.361*xCCHO + 0.38*xRCHO +
         0.283*xIPRD + 0.021*xPROD2 + 1.001*yROOH + 0.747*XC # 3.83e-10;
<BC08> ARO1 + CL = 0.88*xHO2 + 0.88*RO2C + 0.12*RO2XC + 0.12*zRNO3 +
         0.21*xPROD2 + 5.02*XC # 1.00e-10;
<BC09> ARO2 + CL = 0.842*xHO2 + 0.842*RO2C + 0.158*RO2XC + 0.158*zRNO3 +
         0.224*xPROD2 + 6.708*XC # 2.18e-10;
<BC10> TERP + CL = 0.548*HCL + 0.252*xHO2 + 0.068*xCL + 0.034*xMECO3 +
         0.066*xRCO3 + 2.258*RO2C + 0.582*RO2XC + 0.582*zRNO3 + 0.035*CO +
         0.158*xHCHO + 0.218*xRCHO + 0.007*xMGLY + 0.161*xIPRD + 0.007*xAFG1 +
         0.012*xAFG2 + 0.019*xPROD2 + yROOH + 4.356*XC # 5.46e-10;
!
endmech